The solubility of water in the hydrocarbons that comprise crude oil is an increasingly important issue in view of processing, safety and environmental considerations surrounding product quality and equipment sustainability. Water in the reacting hydrocarbon species may result in the formation of undesirable by-products. To illustrate the importance of water solubility in hydrocarbons, we offer the results of solubility studies involving water in benzene derivatives. The results for both solubility and Henry’s Law constant for water are provided in an easy‑to‑use tabular format for a wide variety of benzene derivatives contained in crude oil.... http://www.che.com/processing_and_handling/process_chemicals/Solubility-of-Water-in-Benzene-Derivatives_5499.html
Many reactions, extractions, separations and other operations in the chemical process industries (CPI) involve the use of organic solvents. In addition to handling and disposal issues, organic solvents can pose a number of environmental concerns, such as atmospheric and land toxicity. In many cases, conventional organic solvents are regulated as volatile organic compounds (VOCs). In addition, certain organic solvents are under restriction due to their ozone-layer-depletion potential. Supercritical carbon dioxide is an attractive alternative in place of traditional organic solvents.